Read these 86 OH&S Tips tips to make your life smarter, better, faster and wiser. Each tip is approved by our Editors and created by expert writers so great we call them Gurus. LifeTips is the place to go when you need to know about Ceramics tips and hundreds of other topics.
Keep your people safe
Keep hazardous material under supervision and away from children and untrained personnel. Always keep hazardous and toxic materials in their appropriate workspace. Do not move them into a situation that would allow them to become a hazard.
What materials are toxic?
The two materials that are proven toxic at this time are lead and cadmium. Lead is used to make glazes flow better at low temperatures. Cadmium is used primarily to create bright orange and red colors. There are other materials which may be toxic, but there is not enough evidence that they are unsafe at this time, so they are not regulated. Many of these materials are safe in low doses (for example, nickel, barium, selenium and cobalt), but toxic in high doses. So reducing leaching as much as possible is always a good idea.
Toxic Elements
Silica: Sources- Quartz flint, frits, feldspars clays and glazes
Vanadium: Sources- vanadium pentoxide and ceramic colours.
Cadmium and selenium: Sources- ceramic colours and glazes
Lead: Sources-Lead oxide, frits and glazes
Chromium: Sources- Chrome oxide and some ceramic colours( greens)
Copper: Sources- copper oxide, carbonate and some ceramic colours
Zinc: Sources- zinc oxide, some ceramic colours
Borax: Sources- borax frits
Vanadium Pentoxide
can cause Anemia; it a respiratory irritant.Uranium Compounds
cause kidney damage, not to mention the radioactivity.
For more information on Vanadium Pentoxide, Please see the Article: "Vanadium Pentoxide"
Health and safety data sheets.
When purchasing ceramic material, request individual health and safety data sheets. These will enable you to assess any risk and apply any control measures that may be needed.
Hands should be washed immediately and
thoroughly after handling glaze materials and any
other toxic minerals.
Never ignite a gas kiln without opening the door a
short way first. Accumulated gas can ignite and
explode. Opening the door allows igniting gas to
escape.
Raku OH&S: Sawdust
Always dampen the sawdust to prevent excessive flame and lessen the risk of airborne burning particles.
Raku OH&S: water plunging
Don't drop enclosed or narrow-necked forms abruptly into water, they will explode.
First Aid Kit, safety clothing, eye protection, gloves, etc.
should be easily accessible.
Nickel Oxide
can cause cancer. Will cause skin irritation ('nickel
itch'). Will penetrate skin.
Carbon Monoxide
combines in the body with the hemoglobin in the
blood and reduces the availability of oxygen to the
body. Symptoms such as headache, dizziness and apathy are present in people when 10% of their
hemoglobin combines with carbon monoxide.
Ability to withstand alkaline dishwashing detergents. To test this, mix 50 grams of soda ash in 1 liter of water in a stainless steel pan. Bring to boil. Reduce heat to a simmer. Place samples in the pan, cover, and simmer for 6 hours. Compare the color and surface gloss to a similar but untested sample.
Toxicity in pre-fired form (liquid or dry)
Commercial glaze manufacturers label their glazes using ASTM D-4236. All their glazes are either AP Non-toxic, which means non-toxic in liquid or dry form, or CL Cautions Required, which means it has proper labeling of ingredients for health and safety. In this sense, non-toxic only refers to lead and cadmium.
All glazes sold in K-12 schools must be AP Non-toxic. This is to reduce the risk of harm if a child drinks the glaze. You don't want a lead based glaze in the classroom for example. You will see the AP Non-toxic label on the glaze bottle; a circle with an AP inside.
Remember, all glazes in DRY form are unsafe for breathing, and you should use a good mask whenever dealing with dry glazes. There are chemicals such as manganese which are known to be a health hazard when breathed in dry form, but are not believed to be a problem after being fired. And even clay particles with no toxicity get trapped inside lungs and thus are bad for potters to breathe.
Never brush a kiln shelf with bare hands. Jagged
pieces of glaze or grit stick to the shelf and can
easily tear the skin.
A well ventilated area in the immediate vicinity
of the kiln is mandatory; in fact it is best to have
kilns of all types outside the main studio area thus
eliminating the risk of poisoning yourself with carbon
monoxide, unburnt gas, sulphurous gases, etc., emitted
especially during reduction.
Materials should be stored in a dry place. The large wheeled airtight bins are great for this, and your back!
Plaster should be set aside from these materials.
Testing for toxicity:
Toxic or hazardous materials can also be ingested by the contamination of food by toxic metals released from fired ware. Pottery for domestic use should be tested for metal release and conform to British Standard: 4800 parts 1&2 (Part 2 is for cooking only). Most pottery suppliers will arrange for this test to be carried out.
Kiln vents assist greatly in simplifying firing and reducing firing defects. In addition, they improve element life by removing damaging fumes quickly. Of course, if you are firing in a structure where people are working or living, a vent is required to remove the harmful fumes from the area. This is true for bisque firing as well as glaze firing.
Raku OH&S: Before leaving the site
Thoroughly douse the sawdust-reduction chamber and check the kiln before leaving the site after firing to prevent further smouldering or burning.
Auto cut off and failsafes are preferable and
should be checked periodically.
Powercord extensions
Avoid use of extension cords where they may
intersect areas where traffic is most likely.
Make sure you wear a good dust mask when working with dry ingredients. Clay dust from greenware or from glaze components can get into the lungs and over the years cause emphysema. Whenever possible, wet mop your working area; never sweep with a broom, as this throws dust up into the air, which you might breath in.
Raku OH&S: Kiln area
Ensure that the area around the kiln is clear of debris
Mica, Muscovite,
Vermiculite,
may contain traces of asbestos. Inhalation of dust will
lead to lung irritation, possibly cancer.
Provide Safety gear
Provide control measures for the processes you are undertaking- clothing, masks, extraction systems and washing facilities. Maintain all equipment and have it serviced and checked for effectiveness.
Always turn your off gas at the cylinder. To empty the pipe of gas; guard the pipe to prevent the possibility of burning matter dropping onto it.
Dealing with raw materials
Once measured out, powdered materials should be made into slop form immediately.
Never turn off electrical appliances with wet
hands especially in combination with water on the
floor.
Fire extinguishers should be placed in an
accessible position near the studio. If a fire
developes in the studio and you are keeping a fire
extinguisher there, the heat may prevent you from
reaching it.
Magnesium Oxide
is considered inoxious, but general rules for dusts still apply.
Iron Oxide Dust
is poisonous for children and can cause "iron
pigmentation" of the lungs, supposedly benign but
contentious.
Cleaning the workshop
Adopt wet working and cleaning methods to avoid the creation of airborne dust. All surfaces tools and boards should be washed immediately after use.
Food and drink is best consumed outside the
studio or in an area where contamination by
chemicals, dust in the air, etc., is minimal.
Accessibility of power and light switches: keep
switches and electrical cables away from water or if
this cannot be avoided sufficient protection against
contact should be made.
Incorrect methods of wedging large pieces of
clay may cause injuries, especially to the back.
Damage may occur after a period of several years.
When wedging you should be well aware of your
capabilities of lifting a piece of clay, remembering
that this weight has to be maneouvered at least 21
times before it is wedged. Back and stomach muscles
are strained if the weight is too heavy. Secondly, the
hands should be released from the piece of clay on
the downward movement, just before it makes contact
with its other half, otherwise the sudden curtailing of
momentum at table level creates jarring tremor which
is transferred through the body via the hands, the
latter of which acts as a lever and jerks the spine.
Areas set aside for plaster work should be
cleaned thoroughly after use. Buckets and other
materials used for this work should be for plaster
work only, minimizing the possibility of foreign
mattter fouling up clay.
Ability to withstand thermal shock. This does not mean that you can place a ceramic pan over a flame, or directly into a hot oven. It is very difficult to make pieces that can go directly over flames, and not something an individual should attempt. Ceramic casseroles, etc. should be put into the oven at room temperature, and brought up to temperature slowly. However, your customers might not know this, and even if you tell them, they probably won't remember. To test for thermal shock, place a test pot in the freezer for several hours. Then submerge the piece in a pot of boiling water. (Alternately, put the pot in the sink and pour the boiling water into it.) Repeat this 3 times, looking for minute crazing on the glaze. It is also a good idea to do what a customer would do. Take a completed piece out of the refrigerator, and put it into an already heated oven. Make sure the piece does not crack.
Ability to go from the dishwasher to the microwave. Metal overglazes should never go in the microwave, so it is a good idea to keep them off mugs and other dinnerware items. Other than that, the problem with microwaves is if there is any water trapped inside the clay, it will expand in the microwave and cause the piece to crack. Low fire clays are porous by nature, and always problematic in the microwave. If your glaze is fit very tightly (can withstand the thermal shock test with no crazing), then the glaze may prevent water from getting into the clay, and this will be ok in the microwave. High fire clays should be fired to vitrification to keep water out. (See Tip 17 for more information about vitrification.)
To test microwave safety, take a piece (such as a mug or bowl) and immerse in a pan of water. Bring the water to a boil, then simmer for a few hours. This will allow the piece to absorb water. Then put the piece in the microwave. (The piece should be empty, and you should also put a separate mug of water in the microwave to protect the microwave.) Heat the microwave on high in 10 second increments. After each 10 seconds, carefully touch the piece to see if it is hot. If it has absorbed water, it will heat up. This tells you the piece is not dishwasher safe. You can stop the test when the water in the second mug is boiling.
Resistance to abrasion (does it scratch easily with silverware?). You can test this yourself. It is usually a problem more with matt glazes than shiny.
Raku OH&S: Foot-ware
Wear strong footwear in case you drop red-hot objects.
Spraying OH&S
Never spray any ceramic material outside an adequate extraction booth; ensure the filter is clean and extraction is effective (it should be checked regularly). Wear a mask and protective clothing.
Ferrous Sulphite
can be fatal and should be avoided.
Fiber Blanket
especially in the fired state can shed invisible floating fibres that have similar effects to asbestos.
Like being careful with glazes, occupational health and safety is important when firing, when using various materials, when using toxic components or when using the Raku technique. Learn about OH&S tips and techniques at ceramics.lifetips.com.
Ability to handle acidic foods. To test for acid resistance, slightly squeeze a slice of lemon to get the juices flowing, and leave the whole slice on the glaze overnight. See if the color changes. If it does, there is some leaching going on. A customer could run into this same color change, and there may be chemicals leaking out. Another way to test this is to put a sample in vinegar for 3 days. Finally, there is lab testing, described later.
Safe for Dinnerware Use
This is what most potters are interested in. Can you use a certain glaze on a piece which will contain food and beverages?
Toxicity is one aspect of this. If there is no lead or cadmium in your glaze (including no Frits which contain lead), and your kiln is not contaminated with lead, then you pass one toxicity test (for lead and cadmium). (If you have fired leaded glazes before, your kiln brick may have absorbed lead and could be depositing it on current firings. You can get an inexpensive kit at the hardware store to test your kiln for lead release. And of course you should never fire dinnerware in a kiln with other leaded glazes.)
There are some glazes that have lead or cadmium and still say they are dinnerware safe. They have been fired and tested, and found to pass the test for lead and cadmium release. (A small amount of leaching is allowed by law.) There are also some glazes where the cadmium is encapsulated in other glaze ingredients which traps it when fired. The only caution here is that your firing conditions will be different, so it is possible that your pieces could leach when the test pieces did not. For this reason, it is best to have a sample tested anytime you use glazes which contain lead or cadmium. Later on I will tell you how to do that.
Any time you begin to layer glazes, you are pretty much on your own. Any testing that the manufacturer did will not be applicable. If you don't use any glazes with lead or cadmium as ingredients, you are pretty safe (with the caveats above.) Otherwise, test!
Many potters believe that you should never use these ingredients in dinnerware period. Who knows what may happen to the glaze after years of use, after going through the dishwasher 30 times, after the glazes craze, after they are microwaved and frozen and bombarded with acidic food. It is always possible that a piece will leach lead or cadmium at some point in the future. So to be safe, just avoid them.
Then of course there are the ingredients which are not regulated, but may be toxic especially in high amounts. Unfortunately there is no simple answer to this problem. If you are producing dinnerware then it is advised that you have sample pieces tested for the various ingredients which might be leaching.
Sulpher Dioxide
is a strong lung irritant and can form when firing
soluble metal salts.
Lead is an accumulative poison. It can be stored in the bone structure for years before a fatal dose is accumulated. Beware of raw lead forms, such as white or yellow lead, which are extremely toxic. Use lead frits instead. Do not use for tableware.
For more information on the effects of lead, Please see Article: "Lead"
To check for gas leaks use a gas detector or
soapy water and a brush, but never use a naked
flame.
Carbon Dioxide
If the oxygen level falls, hearing will decrease, pulse and blood pressure rise. Carbon dioxide forms during combustion firing processes.
Raku OH&S: Using LPG
When using liquefied petroleum gas, thoroughly acquaint yourself with the suppliers' recommendations on storage and use.
Ceramic Materials.
When working with ceramic material, avoid creating dust: Some materials are toxic and can quickly have very serious effects upon health, while less hazardous material can still accumulate over a period of time and cause equally serious health problems. Materials in powder form can be inhaled, and materials can also be absorbed through ingestion from contaminated food, cigarettes and drink. Always wash your hands thoroughly on leaving the workshop, and avoid eating, drinking and smoking in the workshop.
Barium Carbonate
A dangerous form of barium, as it forms a soluble
chloride in the stomach and accumulates. It affects
muscles, in particular the heart, increasing its
excitability, leading to high blood pressure and
internal bleeding. Will penetrate the skin. Not
recommended for food ware, as it may leach.
Storing Liquids
Do not allow liquid containing ceramic materials (slip, glazes etc.) to dry out. Always keep liquids in containers with tightly fitting lids and dispose of waste, including contaminated packaging in accordance with the suppliers' instructions.
Raku OH&S: If the gas goes out
Never leave the kiln unattended while firing; If the burner goes out, allow plenty of time for unburnt gas to disperse before re-igniting the burner.
Liquid Petroleum Gas
can cause headaches, numbness, chills and vomiting,
but is a greater risk as explosive than inhalation.
Don't put your hand into operating clay mixers
etc., or you may find yourself neatly blended into the
mix.
Guru Spotlight |
Sheri Ann Richerson |